The Getzler Research Group

“Many bodies have the property of exerting on other bodies an action which is very different from chemical affinity. By means of this action they produce decomposition in bodies, and form new compounds into the composition of which they do not enter. This new power, hitherto unknown, is common both in organic and inorganic nature; I shall call it catalytic power. I shall also call Catalysis the decomposition of bodies by this force.”


Jöns Jacob Berzelius
(Edinburgh New Philosophical Journal, 1836, XXI, 223)

Lab resources - links to useful papers/files/websites...

Here is a great review about sustainable polymerization catalysis.

Please also look at my course websites.

This is a sample of what your lab notebook should look like.

Use this document to order material for the lab.

Use this document to track liquid nitrogen usage.

 

Not sure how to use the NMR software? Check out this handy guide.

Need to reference your spectra to residual solvent? Cambridge Isotope Labs has a chart you can download. And, check out the amazingly useful paper by Gottlieb et. al. which gives the shifts of common impurities in common NMR solvents.

What concentration of analyte does a given NMR experiment need? Check here.

iNMR has a ton of really good info about NMR in general and has some great software for data processing that can help you generate high quality files for papers, reports, theses, etc.

 

TLC Stains - how to make them, which ones are good for what. This comes from the Black Group Research Handbook which has lots of great stuff. And here is a protocol for cutting plates which gives a nice mix of sizes.

 

This chart tells one which solvents a miscible with each other and which are most polar. If you're unsure how to use it, ask me! Thanks to George Lisensky.

Flash Column Chromatography - the original, indispensable paper by Still, Kahn & Mitra

The most useful guide I've found on the web is from REACH Devices. And, if you've got $5k to spare, please buy me one of their detectors.

If you're having trouble separating your compounds, consult this chart and try a different solvent mix (from Thin Layer Chromatography G.B. Marini-Brttolo, p. 77, 1967)

 

What is the pKa of a particular species? Here is an exhaustive list of pKa values compiled by R. Williams.

Alternately you can use this web-based interface to access pKa values. NOTE: THESE ARE IN DMSO, SO BE CAREFUL!

 

You can print out this pressure-temperature nomograph for predicting boiling points at variable pressures (courtesy of Sigma-Aldrich). An applet is also available for making predictions.

Ever had to babysit a dropwise addition for hours on end? Not in the Getzler lab! We've got a nice syringe pump. This document contains the diameters of various syringes.

There is a great databank of azeotrope properties maintained by the University of Edinburgh Chemical Engineering Department

Image modified from a public domain item (Wikipedia).

 

The lab uses an mBraun UniLab. Available documents:

• Operatation of touch screen (6.2 Mb pdf)

• Protocol for box use

 

You probably know what Ac and Ph syand for, but what about Ts, BPOC, TROC?

For that matter, what is TRIS? Or Dess-Martin Periodonane?

Check out this document from Hans Reich at UW Madison (thanks to Paul Bonvallet).

 

 

 

Looking for a reliable way to make a particular chemical? Try Organic Syntheses. If it's there, it's probably gonna work.

Another awesome resource for all things chemical is ChemKnowHow.Com, maintained by the Stoltz Group at Cal Tech.

 

 

 

 

Looking for a good review article, you can search Synthesis Reviews, a database of ~ 2*10^4 reviews in English of interest to synthetic chemists. From 1974 to the middle of last year.

 

 

Need help with a SciFinder search? Try looking here...

Interested in Graduate School? Check out the ACS Directory of Graduate Research (DGR). You can find all sorts of info here about specific faculty and instututions.

Also check out Piled Higher & Deeper (PhD) Comics from Jorge Cham.

The Council on Undergraduate Research (CUR) runs a cool website with tons of resources for undergraduate researchers called WebGURU. Check it out!